ZnCl<sub>2</sub>-mediated stereo- and chemoselective synthesis of vinylphosphonates-Reference-Cited by-同舟云学术

ZnCl₂-mediated stereo- and chemoselective synthesis of vinylphosphonates

Published:2022 Issue:12 Volume:20 Page:2500-2507
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Kaboudin Babak¹^ORCID,Moradi Atieh¹,Esfandiari Hesam¹,Daliri Payam¹,Kazemi Foad¹^ORCID,Yanai Hikaru²^ORCID,Aoyama Hiroshi²

Affiliation:

1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences, Gava Zang, Zanjan, Iran

2. School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan

Abstract

A highly selective synthesis of diethyl (E)-2-(alkylidene)-2-phosphonoacetonitriles via the Knoevenagel condensation reaction of carbonyl compounds with diethyl cyanomethylphosphonate is reported.

Funder

Institute for Advanced Studies in Basic Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D2OB00037G

Reference38 articles.

1. Vinylphosphonates in Organic Synthesis

2. Celebrating 20 Years of SYNLETT - Special Essay: General Procedure for the Palladium-Catalyzed Selective Hydrophosphorylation of Alkynes

3. Transition-Metal-Catalyzed Addition of Heteroatom−Hydrogen Bonds to Alkynes

4. Sequential Double Olefination of 2-(Arylmethylidene)-2-phosphonoacetonitrile with Dimsyl Lithium and Aldehydes: A Domino Route to Densely Substituted 1,3-Butadienes

5. Strategies for the synthesis of α- and β-amino vinylphosphonate

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1. Preparation of Vinylphosphonates from Ketones Promoted by Tf₂O;The Journal of Organic Chemistry;2023-02-21

2. Stereoselective synthesis of vinylphosphonates through aromatic aza-Claisen rearrangement of α-aminophosphonates;Chemical Communications;2023

3. Highly Stereoselective Synthesis of 2, 2‐Disubstituted Vinylphosphonates via Aryl to Vinyl 1, 4‐Palladium Migration;Chinese Journal of Chemistry;2022-07-07