Using sulfur bridge oxidation to control electronic coupling and photochemistry in covalent anthracene dimers-Reference-Cited by-同舟云学术

Using sulfur bridge oxidation to control electronic coupling and photochemistry in covalent anthracene dimers

Published:2019 Issue:32 Volume:10 Page:7561-7573
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cruz Chad D.¹²³⁴,Yuan Jennifer¹⁵⁶⁷^ORCID,Climent Clàudia⁸⁹¹⁰¹¹^ORCID,Tierce Nathan T.¹²³⁴,Christensen Peter R.¹⁵⁶⁷^ORCID,Chronister Eric L.¹²³⁴,Casanova David¹²¹³¹¹¹⁴¹⁵^ORCID,Wolf Michael O.¹⁵⁶⁷^ORCID,Bardeen Christopher J.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of California Riverside

3. California 92521

4. USA

5. University of British Columbia

6. Vancouver

7. Canada V6T 1Z1

8. Departamento de Física Teórica de la Materia Condensada

9. Universidad Autónoma de Madrid

10. E-28049 Madrid

11. Spain

12. Donostia International Physics Center (DIPC)

13. 20018 Donostia

14. IKERBASQUE

15. Basque Foundation for Science

Abstract

For anthracene dimers bridged by a sulfur atom, modulating the sulfur oxidation state profoundly affects excited state behavior. The SO₂-bridge supports long-lived states and photodimerization, while the S-bridge undergoes intersystem crossing.

Funder

Eusko Jaurlaritza

National Science Foundation

H2020 European Research Council

European Regional Development Fund

Ministerio de Economía y Competitividad

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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