Assembly of tetra-nuclear YbIII-containing selenotungstate clusters: synthesis, structures, and magnetic properties

Author:

Han Li-Zhi1,Jiao Cheng-Qi2,Chen Wei-Chao3ORCID,Shao Kui-Zhan3,Jin Long-Yi1ORCID,Su Zhong-Min1ORCID

Affiliation:

1. Department of Chemistry, College of Science, Yanbian University, Yanji 133002, People's Republic of China

2. Liaoning Normal University Liaoning Normal Univ, Sch Chem & Chem Engn, Huanghe Rd 850, Dalian 116029, People's R China

3. Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Northeast Normal University Ren Min Street No. 5268 Changchun, Jilin, 130024, P. R. China

Abstract

The first YbIII-containing POMs with a selenium heteroatom have been isolated, namely Keggin {Yb4Se6W44} and Wells–Dawson {Yb4Se6W45}, the former of which exhibits field-induced SMM behavior.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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