Rhodium-catalyzed double hydroboration of pyridine: the origin of the chemo- and regioselectivities-Reference-Cited by-同舟云学术

Rhodium-catalyzed double hydroboration of pyridine: the origin of the chemo- and regioselectivities

Published:2023 Issue:9 Volume:13 Page:2735-2747
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Choi Hyoju¹²^ORCID,Wang Ruibin³,Kim Suyeon¹²,Kim Dongwook¹²^ORCID,Baik Mu-Hyun¹²^ORCID,Park Sehoon³⁴

Affiliation:

1. Department of Chemistry, Korea Advanced Institute of Science & Technology (KAIST), Daejeon 34341, South Korea

2. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 31341, South Korea

3. Department of Chemistry, Guangdong-Technion Israel Institute of Technology, Shantou, Guangdong 515063, China

4. Technion-Israel Institute of Technology, Technion City, 32000 Haifa, Israel

Abstract

Rhodium catalyzes double hydroboration of pyridine via an unique mechanism involving a Rh-1,2-dihydropyridine adduct to give a mixture of unprecedented tetrahydropyridines bearing a sp3 C–B bond in a specific position.

Funder

Natural Science Foundation of Guangdong Province

Li Ka Shing Foundation

Institute for Basic Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00347G

Reference92 articles.

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2. The Reactivity of N-Substituted Pyridinium Salts

3. Homogeneous catalytic hydrogenation. 6. Synthetic and mechanistic aspects of the regioselective reductions of model coal nitrogen, sulfur, and oxygen heteroaromatic compounds using the (.eta.5-pentamethylcyclopentadienyl)rhodium tris(acetonitrile) dication complex as the catalyst precursor

4. Highly Enantioselective Iridium-Catalyzed Hydrogenation of Heteroaromatic Compounds, Quinolines

5. Recent advances in the chemistry of dihydropyridines

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