The gas-phase infrared spectra of the 2-methylallyl radical and its high-temperature reaction products

Author:

Preitschopf Tobias1ORCID,Hirsch Florian1,Lemmens Alexander K.2ORCID,Rijs Anouk M.2ORCID,Fischer Ingo1ORCID

Affiliation:

1. Institute of Physical and Theoretical Chemistry, University of Wuerzburg, Am Hubland, 97074 Würzburg, Germany

2. Radboud University, Institute for Molecules and Materials, FELIX Laboratory, Toernooiveld 7, 6525 ED Nijmegen, The Netherlands

Abstract

The resonance-stabilized 2-methylallyl radical, 2-MA, is considered as a possible intermediate in the formation of polycyclic aromatic hydrocarbons (PAHs) in combustion processes.

Funder

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

European Commission

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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1. Direct Observation of the Ethyl Radical in the Pyrolysis of Ethane;Angewandte Chemie International Edition;2023-06-28

2. Direct Observation of the Ethyl Radical in the Pyrolysis of Ethane;Angewandte Chemie;2023-06-28

3. IR/UV Double Resonance Study of the 2‐Phenylallyl Radical and its Pyrolysis Products;Chemistry – A European Journal;2023-02

4. Ultraviolet Photodissociation of 2-Methylallyl Radical;Chinese Journal of Chemical Physics;2023

5. Stacking Is Favored over Hydrogen Bonding in Azaphenanthrene Dimers;The Journal of Physical Chemistry Letters;2022-09-22

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