Base-promoted ring-opening/recyclization of naphthoquinones to access benzo[5,6][1,4]thiazino[4,3-<i>b</i>]isoquinoline-7,12-diones at room temperature-Reference-Cited by-同舟云学术

Base-promoted ring-opening/recyclization of naphthoquinones to access benzo[5,6][1,4]thiazino[4,3-b]isoquinoline-7,12-diones at room temperature

Published:2024 Issue:17 Volume:11 Page:4779-4784
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Tan Bin¹,Li Zhuoqin¹,Zhou Xinlin¹,Zhang Chao¹,Deng Guo-Jun¹²^ORCID,Chen Shanping¹

Affiliation:

1. Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, Key Laboratory for Green Organic Synthesis and Application of Hunan. Province, College of Chemistry, Xiangtan University, Xiangtan, 411105, P. R. China

2. School of Chemistry and Chemical Engineering, Henan Normal University Xinxiang, 453007, P. R. China

Abstract

A novel and unique nitrogen atom insertion into naphthoquinone rings to construct structurally valuable polycyclic heterocycles at room temperature under transition-metal-free conditions has been described.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00782D

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5. Catalytic Cleavage of C(sp2)–C(sp2) Bonds with Rh-Carbynoids