Copper-catalysed synthesis of α-alkylidene cyclic carbonates from propargylic alcohols and CO2-Reference-Cited by-同舟云学术

Copper-catalysed synthesis of α-alkylidene cyclic carbonates from propargylic alcohols and CO2

Published:2021 Issue:2 Volume:23 Page:889-897
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Cervantes-Reyes Alejandro¹²³⁴^ORCID,Farshadfar Kaveh⁵⁶⁷⁸⁹^ORCID,Rudolph Matthias¹²³⁴,Rominger Frank¹²³⁴,Schaub Thomas¹⁰¹¹⁴¹²¹³^ORCID,Ariafard Alireza¹⁴¹⁵¹⁶¹⁷^ORCID,Hashmi A. Stephen K.¹²³⁴¹⁰^ORCID

Affiliation:

1. Organisch-Chemisches Institut

2. Heidelberg University

3. 69120 Heidelberg

4. Germany

5. Department of Chemistry

6. Islamic Azad University

7. Central Tehran Branch

8. Tehran 1469669191

9. Iran

10. Catalysis Research Laboratory (CaRLa)

11. Heidelberg

12. BASF SE

13. Ludwigshafen 67056

14. School of Physical Sciences

15. University of Tasmania

16. Hobart TAS 7001

17. Australia

Abstract

A sterically encumbered, nine-membered NHC-copper(i) complex was shown to be an effective catalyst for the chemical fixation of CO₂ by propargylic alcohols for the diastereoselective synthesis of α-alkylidene cyclic carbonates.

Funder

Consejo Nacional de Ciencia y Tecnología

University of Tasmania

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D0GC03990J

Reference93 articles.

1. A short review of catalysis for CO2 conversion