Anion and ether group influence in protic guanidinium ionic liquids

Author:

Rauber Daniel1ORCID,Philippi Frederik2ORCID,Becker Julian2ORCID,Zapp Josef3,Morgenstern Bernd1,Kuttich Björn4,Kraus Tobias14ORCID,Hempelmann Rolf1ORCID,Hunt Patricia25ORCID,Welton Tom2ORCID,Kay Christopher W. M.16

Affiliation:

1. Department of Chemistry, Saarland University, Campus B 2.2, 66123 Saarbrücken, Germany

2. Department of Chemistry, Molecular Sciences Research Hub, Imperial College London, White City Campus, London W12 0BZ, UK

3. Pharmaceutical Biology, Saarland University, Campus B 2.3, 66123 Saarbrücken, Germany

4. INM-Leibniz Institute for New Materials, Campus D2.2, 66123 Saarbrücken, Germany

5. School of Chemical and Physical Sciences, Victoria University of Wellington, New Zealand

6. London Centre for Nanotechnology, University College London, 17-19 Gordon Street, London WC1H 0AH, UK

Abstract

Dynamics and structures of protic ionic liquids from the superbase guanidinium are analyzed in detail. The H-bond strength correlates with the proton affinity of the constituting acid and can be monitored by the 1H or 15N chemical shifts.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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