Light-driven exchange between extended and contracted lasso-like isomers of a bistable [1]rotaxane

Author:

Saura-Sanmartin Adrian12345ORCID,Martinez-Cuezva Alberto12345ORCID,Pastor Aurelia12345ORCID,Bautista Delia6457ORCID,Berna Jose12345ORCID

Affiliation:

1. Departamento de Química Orgánica

2. Facultad de Química

3. Regional Campus of International Excellence “Campus Mare Nostrum”

4. Universidad de Murcia

5. Murcia

6. SAI

7. Spain

Abstract

A photoactive hydrogen-bonded lasso having an amide-based [1]rotaxane structure has been constructed from acyclic precursors through a self-templating approach. The stability, structural integrity and switching are described.

Funder

Ministerio de Economía y Competitividad

Fundación Séneca

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference126 articles.

1. G. Schill , Catenanes, Rotaxanes and Knots , Academic , New York , 1971

2. Molecular Catenanes, Rotaxanes and Knots, A Journey Through the World of Molecular Topology , ed. J.-P. Sauvage and C. Dietrich-Buchecker , Wiley-VCH , Weinheim , 1999

3. C. J. Bruns and J. F.Stoddart , The Nature of the Mechanical Bond: From Molecules to Machines , Wiley , New York , 2016

4. Interlocked and Intertwined Structures and Superstructures

5. Chemical Topology: Complex Molecular Knots, Links, and Entanglements

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