Light-driven exchange between extended and contracted lasso-like isomers of a bistable [1]rotaxane
Author:
Affiliation:
1. Departamento de Química Orgánica
2. Facultad de Química
3. Regional Campus of International Excellence “Campus Mare Nostrum”
4. Universidad de Murcia
5. Murcia
6. SAI
7. Spain
Abstract
A photoactive hydrogen-bonded lasso having an amide-based [1]rotaxane structure has been constructed from acyclic precursors through a self-templating approach. The stability, structural integrity and switching are described.
Funder
Ministerio de Economía y Competitividad
Fundación Séneca
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB02234H
Reference126 articles.
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3. C. J. Bruns and J. F.Stoddart , The Nature of the Mechanical Bond: From Molecules to Machines , Wiley , New York , 2016
4. Interlocked and Intertwined Structures and Superstructures
5. Chemical Topology: Complex Molecular Knots, Links, and Entanglements
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