Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes-Reference-Cited by-同舟云学术

Differences between the elimination of early and late transition metals: DFT mechanistic insights into the titanium-catalyzed synthesis of pyrroles from alkynes and diazenes

Published:2017 Issue:3 Volume:8 Page:2413-2425
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Guo Jiandong¹²³⁴,Deng Xi¹²³⁴,Song Chunyu¹²³⁴,Lu Yu¹²³⁴,Qu Shuanglin¹²³⁴^ORCID,Dang Yanfeng¹²³⁴⁵,Wang Zhi-Xiang¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. University of the Chinese Academy of Sciences

3. Beijing 100049

4. China

5. Collaborative Innovation Center of Chemical Science and Engineering

Abstract

A DFT study demonstrates that titanium is capable of promoting C–N bond formation via an unconventional reductive elimination pathway featuring back-donation (REBD).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC04456E

Reference118 articles.

1. Titanium-Catalyzed Multicomponent Couplings: Efficient One-Pot Syntheses of Nitrogen Heterocycles

2. N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions

3. Reactions and Applications of Titanium Imido Complexes