Order–disorder transition in nano-rutile TiO2 anodes: a high capacity low-volume change Li-ion battery material

Author:

Christensen Christian Kolle12345,Mamakhel Mohammad Aref Hasen67895,Balakrishna Ananya Renuka10111213,Iversen Bo Brummerstedt67895ORCID,Chiang Yet-Ming10111213ORCID,Ravnsbæk Dorthe Bomholdt12345ORCID

Affiliation:

1. Department of Physics

2. Chemistry and Pharmacy

3. University of Southern Denmark

4. 5230 Odense M

5. Denmark

6. Center for Materials Crystallography

7. Department of Chemistry and iNANO

8. Aarhus University

9. 8000 Aarhus C

10. Department of Materials Science and Engineering

11. Massachusetts Institute of Technology

12. Cambridge

13. USA

Abstract

Li-Intercalation in nano-rutile TiO2-anodes induces loss of long-range order with the formation of ∼5 nm layered LixTiO2 domains with ∼1 nm columbite-like grain boundaries.

Funder

Villum Fonden

Det Frie Forskningsråd

Carlsbergfondet

Danmarks Grundforskningsfond

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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