Direct evidence for ligand-enhanced activity of Cu(<scp>i</scp>) sites-Reference-Cited by-同舟云学术

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Direct evidence for ligand-enhanced activity of Cu(i) sites

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dongmo Elvira Gouatieu¹²^ORCID,Haque Shabnam¹^ORCID,Kreuter Florian¹^ORCID,Wulf Toshiki¹³^ORCID,Jin Jiaye¹^ORCID,Tonner-Zech Ralf¹^ORCID,Heine Thomas²³⁴^ORCID,Asmis Knut R.¹^ORCID

Affiliation:

1. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, 04103 Leipzig, Germany

2. Institute of Resource Ecology, Research Site Leipzig, Helmholtz-Zentrum Dresden-Rossendorf, Permoserstr. 15, 04318 Leipzig, Germany

3. Faculty of Chemistry and Food Chemistry, School of Science, TU Dresden, 01062 Dresden, Germany

4. Department of Chemistry and ibs for Nanomedicine, Yonsei University, Seodaemun-gu, Seoul 120-749, Republic of Korea

Abstract

Cu(i) sites enhance their activity upon coordination with oxygen-donor ligands, as demonstrated by infrared photodissociation spectroscopy and ab initio calculations.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC04582C

Reference44 articles.

1. Air-Stable Cu(I) Metal–Organic Framework for Hydrogen Storage

2. Observation of an Intermediate to H2 Binding in a Metal–Organic Framework

3. Highly effective hydrogen isotope separation through dihydrogen bond on Cu(I)-exchanged zeolites well above liquid nitrogen temperature

4. H2 Adsorption on Cu(I)–SSZ-13

5. Capture of heavy hydrogen isotopes in a metal-organic framework with active Cu(I) sites

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