Formation of dications bearing a S(OH)2+ group from long-lived 9,9-dimethyl-10 R-phenanthrenium cations in FSO3H–SbF5/SO2ClF/SO2: a mechanistic study
Author:
Affiliation:
1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
2. Novosibirsk 630090, Russian Federation
Abstract
A key step in the reaction mechanism is addition of SO2 to the superelectrophilic intermediates – protonated phenanthrenium cations.
Funder
Russian Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA11673A
Reference21 articles.
1. Stable carbonium ions. IC. Benzenonium ion (C6H7+) and its degenerate rearrangement
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4. Stable carbonium ions. LI. Fluorobenzenonium ions
5. Stable carbonium ions. LXI. Methylfluorobenzenonium ions
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