Isocyanide insertion into Au–H bonds: first gold iminoformyl complexes-Reference-Cited by-同舟云学术

Isocyanide insertion into Au–H bonds: first gold iminoformyl complexes

Published:2018 Issue:81 Volume:54 Page:11447-11450
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fernandez-Cestau Julio¹²³^ORCID,Rocchigiani Luca¹²³^ORCID,Pintus Anna¹²³^ORCID,Rama Raquel J.¹²³⁴⁵^ORCID,Budzelaar Peter H. M.⁶⁷⁸^ORCID,Bochmann Manfred¹²³^ORCID

Affiliation:

1. School of Chemistry, University of East Anglia

2. Norwich

3. UK

4. Departamento de Química Inorgánica, Universidad de Sevilla

5. E-41092 Sevilla

6. Department of Chemistry, University of Naples Federico II

7. Naples

8. Italy

Abstract

The reaction of gold hydrides with isocyanides leads to η¹-iminoformyl complexes, the first example of an isocyanide insertion in gold chemistry. Key intermediates are gold(ii) isocyanide adducts.

Funder

FP7 Ideas: European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06409A

Reference50 articles.

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5. Reactions of Isocyanides with Metal Carbyne Complexes: Isolation and Characterization of Metallacyclopropenimine Intermediates

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