Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions-Reference-Cited by-同舟云学术

Controlling the organization of phosphonium cations relative to p-sulfonatocalix[4]arene anions

Published:2015 Issue:7 Volume:17 Page:1526-1530
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Ling Irene¹²³⁴⁵,Sobolev Alexandre N.⁶⁷⁸,Raston Colin L.⁵⁹¹⁰⁸

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. University of Malaya

4. 50603 Kuala Lumpur, Malaysia

5. Centre for NanoScale Science and Technology

6. School of Chemistry and Biochemistry

7. M310, The University of Western Australia

8. , Australia

9. School of Chemical and Physical Sciences

10. Flinders University

Abstract

A composite material containing supermolecules of 1,4-bis(triethylammoniomethyl)benzene and p-sulfonated calix[4]arene involves preferential binding of the ammonium moieties in the cavities of two geometrically opposed calixarenes with mono-phosphonium cations arranged in the endo-orientation with respect to the calixarene bilayers, as a multi-layered structure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CE/C4CE02086C

Reference32 articles.

1. Controlling the interplay of large organic ions: para-sulfonato-calix[4]arene and phosphonium cations

2. Nanoporous materials based on heteroleptic bilayers built up from bisphosphonium, p-sulfonatocalix[4]arene ions

3. Natrium-calix[4]arensulfonate, Komplexe mit neuartiger Schichtstruktur – ein organischer Ton?

4. Organic clays. Synthesis and structure of Na5[calix[4] arene sulfonate] � 12 H2O, K5[calix[4]arene sulfonate]�8 H2O, Rb5[calix[4]arene sulfonate]�5 H2O, and Cs5[calix[4] arene sulfonate] �4 H2O

5. Non-covalent expansion of an organic bilayer involving exo-cavity interplay of tetraphenylphosphonium with para-sulfonato-calix[4]arene

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