Reduction of aromatic nitriles into aldehydes using calcium hypophosphite and a nickel precursor-Reference-Cited by-同舟云学术

Reduction of aromatic nitriles into aldehydes using calcium hypophosphite and a nickel precursor

Published:2018 Issue:35 Volume:16 Page:6600-6605
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Mouselmani Rim¹²³⁴⁵,Hachem Ali⁶⁷⁸⁹¹⁰,Alaaeddine Ali⁶⁷⁸⁹¹⁰,Métay Estelle¹²³⁴⁵^ORCID,Lemaire Marc¹²³⁴⁵^ORCID

Affiliation:

1. Laboratoire de Catalyse

2. Synthèse et Environnement

3. Institute de Chimie et Biochimie Moléculaires et Supramoléculaire (ICBMS)

4. CNRS

5. UMR 5246

6. Laboratoire de Chimie Médicinale et des Produits Naturels

7. Université Libanaise

8. Campus Universitaire Rafic Hariri Hadath

9. Beirut

10. Lebanon

Abstract

The reduction of aromatic nitriles to aldehydes is performed with good to excellent yields and selectivities. Calcium hypophosphite is used in the presence of nickel(ii) catalyst and base in a water/ethanol system.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB01751D

Reference52 articles.

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3. Samarium(II)-Iodide-Mediated Cyclizations in Natural Product Synthesis

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