Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors-Reference-Cited by-同舟云学术

Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors

Published:2015 Issue:45 Volume:44 Page:19615-19624
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Cheng-Pan¹²³⁴,Xi Zhenxing¹²³⁴,Mueller Kory M.¹⁵⁶⁴,Holliday Bradley J.¹⁵⁶⁴,Bazzi Hassan S.¹⁷⁸⁹,Gladysz John A.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Texas A&M University

3. College Station

4. USA

5. The University of Texas at Austin

6. Austin

7. Texas A&M University at Qatar

8. Doha

9. Qatar

Abstract

The title compounds, [Q]₂[Fe₄S₄(S(CH₂)_nR_f8)₄], feature dianions with four fluorous thiolate ligands and cations that are non-fluorous, “light fluorous”, or “heavy fluorous”; fluorous/organic partition coefficients can reach >93 : <7.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01959A

Reference77 articles.

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