Nucleophilic addition of tertiary propargylic amines to arynes followed by a [2,3]-sigmatropic rearrangement-Reference-Cited by-同舟云学术

Nucleophilic addition of tertiary propargylic amines to arynes followed by a [2,3]-sigmatropic rearrangement

Published:2018 Issue:47 Volume:54 Page:6036-6039
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhou Meng-Guang¹²³⁴⁵,Dai Rui-Han¹²³⁴⁵,Tian Shi-Kai¹²³⁴⁵^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale

2. Center for Excellence in Molecular Synthesis, and Department of Chemistry

3. University of Science and Technology of China

4. Hefei

5. China

Abstract

Treatment of tertiary propargylic amines with 2-(trimethylsilyl)aryl triflates under mild conditions provides convenient access to amino-substituted allenes or conjugated dienes.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC02176G

Reference55 articles.

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