Fourier-transform microwave spectroscopy of the s-trans-3-propenalyl (CH2CHĊO) and 3-propenolyl (ĊH2CHCO) radicals-Reference-Cited by-同舟云学术

Fourier-transform microwave spectroscopy of the s-trans-3-propenalyl (CH₂CHĊO) and 3-propenolyl (ĊH₂CHCO) radicals

Published:2023 Issue:48 Volume:25 Page:33112-33118
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Liu Yi-Ting¹,Chang Ching-Hua¹,Nakajima Masakazu²^ORCID,Endo Yasuki¹^ORCID

Affiliation:

1. Department of Applied Chemistry, National Yang Ming Chiao Tung University, Science Building II, 1001 Ta-Hsueh Rd., Hsinchu 300093, Taiwan

2. Department of Basic Science, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

Abstract

Two conformers of an open-shell radical, CH2CHCO, are observed by Fourier-transform microwave spectroscopy, where the bent s-trans form was found to be the lowest energy conformer.

Funder

Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP05210A

Reference16 articles.

1. A CASSCF Study on Photodissociation of Acrolein in the Gas Phase

2. A Kinetic and Mechanistic Study of the Reaction of Cl Atoms with Acrolein: Temperature Dependence for Abstraction Channel

3. Photolysis of Matrix-Isolated Acryloyl Chloride: 1,3 Chlorine Migration and Further Evolutions

4. 193-nm photodissociation of acryloyl chloride to probe the unimolecular dissociation of CH2CHCO radicals and CH2CCO

5. Probing the barrier for CH2CHCO→CH2CH+CO by the velocity map imaging method

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