Coupling of CO2 and epoxides catalysed by novel N-fused mesoionic carbene complexes of nickel(ii)-Reference-Cited by-同舟云学术

Coupling of CO2 and epoxides catalysed by novel N-fused mesoionic carbene complexes of nickel(ii)

Published:2021 Issue:46 Volume:50 Page:17361-17371
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Watt Fabian A.¹,Sieland Benedikt¹,Dickmann Nicole¹,Schoch Roland¹,Herbst-Irmer Regine²^ORCID,Ott Holger³^ORCID,Paradies Jan¹^ORCID,Kuckling Dirk¹,Hohloch Stephan⁴^ORCID

Affiliation:

1. Paderborn University, Faculty of Science, Department of Chemistry, Warburger Straße 100, 33098 Paderborn, Germany

2. University of Göttingen, Institute of Inorganic Chemistry, Tammannstraße 4, 37077 Göttingen, Germany

3. Bruker AXS GmbH, Östliche Rheinbrückenstraße 49, 76187 Karlsruhe, Germany

4. University of Innsbruck, Faculty of Chemistry and Pharmacy, Institute of General, Inorganic and Theoretical Chemistry, Innrain 80-82, 6020 Innsbruck, Austria

Abstract

While mesoionic carbenes have usually been shown to improve the catalytic potential of metal complexes, here, we report a switch of selectivity in the nickel-catalyzed coupling of CO2 and epoxides, now favoring cyclic carbonates over polycarbonates.

Funder

Universität Paderborn

Universität Innsbruck

Verband der Chemischen Industrie

Daimler und Benz Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03311E

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