Dopant-induced cationic bivalency in hierarchical antimony-doped tin oxide nano-particles for room-temperature SO2 sensing

Author:

Chakraborty Nirman1,Ghose Pradeepta Kumar2,Rudra Pratyasha1,Das Sagnik1,Saha Debdulal1,Mishra Ajay K.3,Sanyal Ambarish1,Mondal Swastik1ORCID

Affiliation:

1. CSIR Central Glass and Ceramic Research Institute, 196, Raja S. C. Mullick Road, Jadavpur, Kolkata-700032, India

2. School of Physical Sciences, Indian Association for the Cultivation of Science, Jadavpur, 2A and 2B Raja S.C. Mullick Road, Kolkata-700032, India

3. High Pressure & Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085, India

Abstract

Antimony doping in tin oxide triggered generation of tin bivalency and it is the variation in ratio of 2+ and 4+ states of tin that determines the efficiency of room temperature SO2 sensing.

Funder

Science and Engineering Research Board

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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