From BaAlBO3F2 to BaAlB3O6F2 and BaAl2(B3O6)2F2: the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups-Reference-Cited by-同舟云学术

From BaAlBO₃F₂ to BaAlB₃O₆F₂ and BaAl₂(B₃O₆)₂F₂: the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

Published:2024 Issue:18 Volume:11 Page:6020-6027
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Chen Cheng¹,Dou Danyang¹,Bai Yunjie¹,Zhang Bingbing¹²^ORCID,Wang Ying¹²^ORCID

Affiliation:

1. College of Chemistry and Materials Science, Hebei Research Center of the Basic Discipline of Synthetic Chemistry, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education, Key Laboratory of Chemical Biology of Hebei Province, Hebei University, Baoding 071002, China

2. Institute of Life Science and Green Development, Hebei University, Baoding 071002, China

Abstract

Two new fluoroaluminoborates, BaAlB3O6F2 and BaAl2(B3O6)2F2, were designed and synthesized, exhibiting a markedly elevated birefringence in comparison with BaAlBO3F2.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province

Hebei University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D4QI01530D

Reference53 articles.

1. Borates: A Rich Source for Optical Materials

2. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

3. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

4. Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides

5. Short history of laser development