Linearly bridging CO2 in a metal–organic framework-Reference-Cited by-同舟云学术

Linearly bridging CO2 in a metal–organic framework

Published:2015 Issue:40 Volume:51 Page:8446-8449
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yi Fei-Yan¹²³⁴⁵,Jiang Hai-Long⁶⁷⁸⁹¹⁰,Sun Zhong-Ming¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences (CAS)

4. Changchun

5. China

6. Hefei National Laboratory for Physical Sciences at the Microscale

7. Collaborative Innovation Center of Suzhou Nano Science and Technology

8. Department of Chemistry

9. University of Science and Technology of China

10. Hefei

Abstract

A very rare CO₂-coordinated metal–organic framework was structurally confirmed by single-crystal X-ray diffraction. The CO₂ ligand links two open Zn metal centers in an absolutely linear μ(O,O′) coordination mode with a CO distance of 1.107(4) Å. The new complex reported here is stable under ambient conditions and may provide a new strategy for CO₂ fixation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC01244A

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4. Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal–Organic Frameworks

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