Iridium-catalyzed α-alkynylation of cyclic nonaromatic eneformamides: application to the synthesis of azapolycyclic architectures-Reference-Cited by-同舟云学术

Iridium-catalyzed α-alkynylation of cyclic nonaromatic eneformamides: application to the synthesis of azapolycyclic architectures

Published:2019 Issue:12 Volume:43 Page:4664-4668
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Beng Timothy K.¹²³⁴^ORCID,Wanjiku Francine¹²³⁴

Affiliation:

1. Department of Chemistry

2. Central Washington University

3. Ellensburg

4. USA

Abstract

A regioselective and chelation-assisted dehydrogenative alkynylation of cyclic nonaromatic eneformamides with terminal alkynes, under iridium catalysis, is described.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ00003H

Reference46 articles.

1. Direct Metal‐Catalyzed Regioselective Functionalization of Enamides

2. Enantioselective cyclization of enamide-ynes and application to the synthesis of the kopsifoline core

3. Gold-Catalysed Synthesis of Exocyclic Vinylogous Amides and β-Amino Ketones: A Detailed Study on the 5-exo/6-endo-digSelectivity, Methodology and Scope

4. Synthesis of Vinylogous Amides by Gold(I)-Catalyzed Cyclization of N-Boc-Protected 6-Alkynyl-3,4-dihydro-2H-pyridines

5. Use of Nonfunctionalized Enamides and Enecarbamates in Asymmetric Synthesis

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