A thermo-responsive MOF-based H2O2-in-oil “pickering emulsion in situ catalytic system” for highly efficient olefin epoxidation-Reference-Cited by-同舟云学术

A thermo-responsive MOF-based H₂O₂-in-oil “pickering emulsion in situ catalytic system” for highly efficient olefin epoxidation

Published:2022 Issue:15 Volume:3 Page:6298-6306
ISSN:2633-5409
Container-title:Materials Advances
language:en
Short-container-title:Mater. Adv.

Author:

Huang Bin¹,Jiang Wei-Ling²,Han Jie³,Niu Yan-Fei¹,Wu Hai-Hong¹^ORCID,Zhao Xiao-Li¹^ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China

2. Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, P. R. China

3. Department of Science, School of Science and Technology, Hong Kong Metropolitan University, Hong Kong SAR, P. R. China

Abstract

A thermo-responsive MOF has been designed as a highly efficient Pickering emulsifier to stabilize the H2O2-in-oil emulsion. The resultant emulsion displayed good catalytic performance in epoxidation of olefins and easy catalyst-product separation.

Funder

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2022/MA/D2MA00245K

Reference48 articles.

1. Epoxidation of olefins with hydrogen peroxide catalyzed by polyoxometalates

2. Amphiphilic phosphotungstate-paired ionic copolymer as a highly efficient catalyst for triphase epoxidation of alkenes with H2O2

3. Development of a New Triphase Catalyst and Its Application to the Epoxidation of Allylic Alcohols

4. Trapping of a Highly Reactive Oxoiron(IV) Complex in the Catalytic Epoxidation of Olefins by Hydrogen Peroxide

5. Chromium(III) Terephthalate Metal Organic Framework (MIL-101): HF-Free Synthesis, Structure, Polyoxometalate Composites, and Catalytic Properties

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