Group 3 metal trihalide complexes with neutral N-donor ligands – exploring their affinity towards fluoride

Author:

Curnock Emily1234,Levason William1234ORCID,Light Mark E.1234,Luthra Sajinder K.5674,McRobbie Graeme5674ORCID,Monzittu Francesco M.1234ORCID,Reid Gillian1234ORCID,Williams R. Nathan1234

Affiliation:

1. Chemistry

2. University of Southampton

3. Southampton SO17 1BJ

4. UK

5. GE Healthcare

6. The Grove Centre

7. Amersham HP7 9LL

Abstract

Fluorination of [ScCl3(Me3-tacn)] and [ScCl3(BnMe2-tacn)] by Cl/F exchange with anhydrous [NMe4]F in CH3CN solution yields the corresponding [ScF3(R3-tacn)].

Funder

GE Healthcare

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference59 articles.

1. Scandium , ed. C. T. Horovitz , Academic Press , London , 1976

2. F. A. Hart , Comprehensive Coordination Chemistry I , ed. G. Wilkinson , R. D. Gillard and J. A. McCleverty , Pergamon , Oxford , 1987 , vol. 3 , p. 1060

3. S. A. Cotton , Comprehensive Coordination Chemistry II , ed. J. A. McCleverty and T. J. Meyer , Elsevier , Oxford , 2004 , vol. 3 , p. 93

4. K. J. Fisher , Comprehensive Coordination Chemistry II , ed. J. A. McCleverty and T. J. Meyer , Elsevier , Oxford , 2004 , vol. 4 , p. 1

5. Structural properties of scandium inorganic salts

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