Accelerating hydrogen evolution at neutral pH by destabilization of water with a conducting oxophilic metal oxide

Author:

Xie Zhengzhe12345,Wang Wugang67894ORCID,Ding Ding10111294,Zou Yu12345ORCID,Cui Yi10111294,Xu Lai67894ORCID,Jiang Jiang12345ORCID

Affiliation:

1. School of Nano-Tech and Nano-Bionics

2. University of Science and Technology of China

3. Hefei

4. China

5. i-Lab

6. Institute of Functional Nano & Soft Materials (FUNSOM)

7. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices

8. Soochow University

9. Suzhou

10. Vacuum Interconnected Nanotech Workstation

11. Suzhou Institute of Nano-Tech and Nano-Bionics

12. Chinese Academy of Sciences

Abstract

Self-supporting Ni4Mo–V2O3 nanosheets, which combine oxophilic V2O3 as a water dissociation center with Ni4Mo as a proton recombination site, display an extremely low overpotential (39.3 mV at 10 mA cm−2) for hydrogen evolution at neutral pH.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Higher Education Discipline Innovation Project

Collaborative Innovation Center of Suzhou Nano Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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