RNA-inspired intramolecular transesterification accelerates the hydrolysis of polyethylene-like polyphosphoesters-Reference-Cited by-同舟云学术

RNA-inspired intramolecular transesterification accelerates the hydrolysis of polyethylene-like polyphosphoesters

Published:2021 Issue:48 Volume:12 Page:16054-16064
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Haider Tobias P.¹,Suraeva Oksana¹,Lieberwirth Ingo¹^ORCID,Paneth Piotr²^ORCID,Wurm Frederik R.³^ORCID

Affiliation:

1. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

2. International Center for Research on Innovative Biobased Materials (ICRI-BioM), Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland

3. Sustainable Polymer Chemistry, Department of Molecules and Materials, MESA+ Institute for Nanotechnology, Faculty of Science and Technology, Universiteit Twente, PO Box 217, 7500 AE Enschede, The Netherlands

Abstract

RNA-inspired degradation of polyethylene-like polyphosphoesters accelerates the backbone hydrolysis dramatically to guarantee seawater-degradable plastics.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Fundacja na rzecz Nauki Polskiej

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC05509G

Reference38 articles.

1. Poly(alkylene phosphates): From Synthetic Models of Biomacromolecules and Biomembranes toward Polymer−Inorganic Hybrids (Mimicking Biomineralization)