Pathway bifurcations in the cage rearrangement of metallacarboranes: experimental and computational evidence-Reference-Cited by-同舟云学术

Pathway bifurcations in the cage rearrangement of metallacarboranes: experimental and computational evidence

Published:2021 Issue:1 Volume:50 Page:287-293
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vinogradov Mikhail M.¹²³⁴^ORCID,Nesterov Ivan D.⁵²³⁴,Nelyubina Yulia V.¹²³⁴,Pavlov Alexander A.¹²³⁴^ORCID

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds

2. Russian Academy of Sciences

3. Moscow 119991

4. Russian Federation

5. N. D. Zelinsky Institute of Organic Chemistry

Abstract

Thirteen new metallacarborane complexes of rhodium and iridium with covalently bound cage carbon atoms were synthesized and their thermal stability was investigated.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03538F

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4. Experimental and Computational Evidence for Gold Vinylidenes: Generation from Terminal Alkynes via a Bifurcation Pathway and Facile C–H Insertions

5. Mechanistic Switch in Dual Gold Catalysis of Diynes: C(sp3)-H Activation through Bifurcation-Vinylidene versus Carbene Pathways

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