Controlling tunnelling in methane loss from acetone ions by deuteration
Author:
Affiliation:
1. Molecular Dynamics Group
2. Paul Scherrer Institute
3. Villigen 5232
4. Switzerland
5. Department of Chemistry
6. University of North Carolina
7. Chapel Hill
8. USA
9. Hiram College
10. Hiram
Abstract
Methane loss is predominantly a result of quantum tunnelling in acetone cations, and it can be suppressed quantitatively by deuteration.
Funder
American Chemical Society Petroleum Research Fund
Bundesamt für Energie
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP02944A
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