Extraction and complexation studies with 2,6-bis(5-(<i>tert</i>-butyl)-1<i>H</i>-pyrazol-3-yl)pyridine in the presence of 2-bromohexanoic acid-Reference-Cited by-同舟云学术

Extraction and complexation studies with 2,6-bis(5-(tert-butyl)-1H-pyrazol-3-yl)pyridine in the presence of 2-bromohexanoic acid

Published:2024 Issue:39 Volume:14 Page:28415-28422
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Stracke Jonas¹²^ORCID,Weßling Patrik²,Sittel Thomas¹^ORCID,Meiners Paul²,Geist Andreas¹^ORCID,Panak. Petra J.¹²

Affiliation:

1. Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe, Germany

2. Heidelberg University, Institut für Physikalische Chemie, Im Neuenheimer Feld 253, 69120 Heidelberg, Germany

Abstract

Extraction studies of An(iii) and Ln(iii) with C4-BPP showed an excellent separation factor of SFAm(iii)/Eu(iii) ≈ 200 due to [Eu(C4-BPP)2(2-bromohexanoate)m](3−m)+ (m = 1–3). In contrast, Cm(iii) forms significantly more stable homoleptic complexes.

Funder

Bundesministerium für Bildung und Forschung

Bundesministerium für Wirtschaft und Klimaschutz

Bundesministerium für Umwelt, Naturschutz, nukleare Sicherheit und Verbraucherschutz

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA05630B

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