Atmospheric sink of methyl chlorodifluoroacetate and ethyl chlorodifluoroacetate: temperature dependent rate coefficients, product distribution of their reactions with Cl atoms and CF2ClC(O)OH formation-Reference-Cited by-同舟云学术

Atmospheric sink of methyl chlorodifluoroacetate and ethyl chlorodifluoroacetate: temperature dependent rate coefficients, product distribution of their reactions with Cl atoms and CF2ClC(O)OH formation

Published:2016 Issue:57 Volume:6 Page:51834-51844
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Blanco María B.¹²³⁴⁵,Barnes Ian⁶⁷⁸⁹¹⁰,Wiesen Peter⁶⁷⁸⁹¹⁰,Teruel Mariano A.¹²³⁴⁵

Affiliation:

1. CONICET

2. Instituto de Investigaciones en Fisicoquímica

3. I.N.F.I.Q.C.

4. Facultad de Ciencias Químicas

5. Universidad Nacional de Córdoba

6. Bergische Universität Wuppertal

7. Fakultät für Mathematik und Naturwissenschaften

8. Physikalische & Theoretische Chemie

9. 42119 Wuppertal

10. Germany

Abstract

Rate coefficients as a function of temperature and product distribution studies have been performed for the first time for the gas-phase reactions of chlorine atoms with methyl chlorodifluoracetate (k₁) and ethyl chlorodifluoroacetate (k₂) using the relative rate technique.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA03454C

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