Site selective gold(<scp>i</scp>)-catalysed benzylic C–H amination <i>via</i> an intermolecular hydride transfer to triazolinediones-Reference-Cited by-同舟云学术

Site selective gold(i)-catalysed benzylic C–H amination via an intermolecular hydride transfer to triazolinediones

Published:2023 Issue:36 Volume:14 Page:9787-9794
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bevernaege Kevin¹,Tzouras Nikolaos V.²^ORCID,Poater Albert³^ORCID,Cavallo Luigi⁴^ORCID,Nolan Steven P.⁵^ORCID,Nahra Fady²⁵^ORCID,Winne Johan M.¹^ORCID

Affiliation:

1. Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281-S4, B-9000 Ghent, Belgium

2. Department of Chemistry and Center for Sustainable Chemistry, Ghent University, Krijgslaan 281-S3, B-9000 Ghent, Belgium

3. Departament de Química, Institut de Química Computacional i Catàlisi, Universitat de Girona, C/Maria Aurèlia Capmany 69, 17003 Girona, Spain

4. KAUST Catalysis Center, Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal, 23955, Saudi Arabia

5. Separation and Conversion Technology, VITO (Flemish Institute for Technological Research), Boeretang 200, 2400 Mol, Belgium

Abstract

A swift C–H amination protocol is reported for alkylbenzenes, which shows a remarkable discrimination of C–H bonds, following small differences in substitution pattern. This is rationalized by an unusual rate-determining hydride transfer.

Funder

Fonds Wetenschappelijk Onderzoek

Ministerio de Ciencia e Innovación

Bijzonder Onderzoeksfonds UGent

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03683A

Reference63 articles.

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5. An aziridinium imide intermediate in the ene reaction of trans-cycloheptene and N-methyl-1,2,4-triazoline-3,5-dione

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