Direct catalytic cross-coupling of alkenyllithium compounds

Author:

Hornillos Valentín1234,Giannerini Massimo1234,Vila Carlos1234,Fañanás-Mastral Martín1234,Feringa Ben L.1234

Affiliation:

1. Stratingh Institute for Chemistry

2. University of Groningen

3. 9747 AG Groningen

4. The Netherlands

Abstract

The direct cross-coupling of alkenyllithium reagents with aryl and alkenyl halides is described. The use of a catalyst comprising Pd2(dba)3/XPhos allows for the stereoselective preparation of a wide variety of substituted alkenes in high yields under mild conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference69 articles.

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