Engineering an electrostatic field layer for high-rate and dendrite-free Zn metal anodes

Author:

Zhu Kaiping1,Guo Can2,Gong Wenbin3,Xiao Qinghua4,Yao Yagang1,Davey Kenneth5ORCID,Wang Qinghong4ORCID,Mao Jianfeng5ORCID,Xue Pan6,Guo Zaiping5ORCID

Affiliation:

1. College of Engineering and Applied Sciences, Nanjing University, Nanjing, Jiangsu 210093, China

2. School of Chemistry, South China Normal University, Guangzhou, Guangdong 510006, China

3. School of Physics and Energy, Xuzhou University of Technology, Xuzhou, Jiangsu 221018, China

4. School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu 221116, China

5. School of Chemical Engineering, The University of Adelaide, Adelaide 5005, Australia

6. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Abstract

The Co(TAPC) additive can be preferentially adsorbed on the Zn anode surface to create a dense zincophilic molecular layer. The layer could promote the desolvation of Zn2+and redistribute the Zn2+flux, resulting in smooth and stable Zn deposition.

Funder

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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