Zinc peroxide as a convenient and recyclable source of anhydrous hydrogen peroxide and its application in the peroxidation of carbonyls

Author:

Radulov Peter S.1ORCID,Mikhaylov Alexey A.2ORCID,Medvedev Alexander G.2ORCID,Barsegyan Yana A.1ORCID,Belyaev Evgeny S.3ORCID,Dmitrieva Victoria E.14ORCID,Tripol'skaya Tatyana A.2ORCID,Mel’nik Elena A.2ORCID,Vil’ Vera A.1ORCID,Yaremenko Ivan A.1ORCID,Prikhodchenko Petr V.2ORCID,Terent’ev Alexander O.1ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prosp., 119991, Moscow, Russian Federation

2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp., 119991, Moscow, Russian Federation

3. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Leninskii Pr. 31-4, Moscow, 119071, Russian Federation

4. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Square, 125047, Moscow, Russian Federation

Abstract

This study reports a convenient, safe and recyclable source of anhydrous H2O2 for organic peroxide synthesis. It is based on the generation of H2O2 through the reaction of ZnO2 with H2SO4 and the recycling of ZnO2 from ZnSO4 and 1 wt% H2O2.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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