Electron transfer vs. proton-coupled electron transfer as the mechanism of reaction between amino acids and triplet-excited benzophenones revealed by time-resolved CIDNP-Reference-Cited by-同舟云学术

Electron transfer vs. proton-coupled electron transfer as the mechanism of reaction between amino acids and triplet-excited benzophenones revealed by time-resolved CIDNP

Published:2018 Issue:32 Volume:20 Page:21127-21135
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Morozova Olga B.¹²³⁴²^ORCID,Panov Mikhail S.¹²³⁴²^ORCID,Fishman Natalya N.¹²³⁴²^ORCID,Yurkovskaya Alexandra V.¹²³⁴²^ORCID

Affiliation:

1. International Tomography Center

2. 630090 Novosibirsk

3. Russia

4. Novosibirsk State University

Abstract

We use proportionality between NMR signal enhancements in geminate products and hyperfine coupling constants in transient radicals to elucidate reaction mechanism in detail.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP03591A

Reference44 articles.

1. Biochemistry and Theory of Proton-Coupled Electron Transfer

2. Theory of Coupled Electron and Proton Transfer Reactions

3. Proton-Coupled Electron Transfer in DNA on Formation of Radiation-Produced Ion Radicals