Hydrogen bonding-promoted efficient Ru-catalyzed ring-closing metathesis of demanding homoallyl 2-(hydroxymethyl)acrylates-Reference-Cited by-同舟云学术

Hydrogen bonding-promoted efficient Ru-catalyzed ring-closing metathesis of demanding homoallyl 2-(hydroxymethyl)acrylates

Published:2016 Issue:45 Volume:14 Page:10705-10713
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Feng Liang¹²³⁴,Liu Yuehui¹²³⁴,Hou Bo⁵⁶⁷⁸⁴,Yuan Zaifeng¹²³⁴,Yu Fu-Chao¹²³⁴,Yan Tingbin¹²³⁴,Qin Qi¹²³⁴,Ji Ruigeng¹²³⁴,Li Ya-Min¹²³⁴,Shen Yuehai¹²³⁴,Zuo Zhi-Li⁵⁶⁷⁸⁴

Affiliation:

1. Faculty of Life Science and Technology

2. Kunming University of Science and Technology

3. Kunming 650500

4. China

5. State Key Laboratory of Phytochemistry and Plant Resources in West China

6. Kunming Institute of Botany

7. Chinese Academy of Sciences

8. Kunming 650201

Abstract

An efficient Ru-catalyzed RCM of sterically demanding homoallyl 2-(hydroxymethyl)acrylates was developed. The unusual directing effect of OH⋯Cl hydrogen bonding was disclosed by experimental and computational approaches.

Funder

Kunming University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB02129H

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