Harnessing magnetic fields for rare-earth complex crystallization–separations in aqueous solutions

Author:

Kumar Amit1ORCID,Geng Han1ORCID,Schelter Eric J.1ORCID

Affiliation:

1. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 S. 34th St., Philadelphia, PA, 19104, USA

Abstract

Magnetic crystallization was used as an energy-efficient technique for selective separation of paramagnetic rare-earth ions from lanthanum ions. An air-stable and simple RE-DOTA complex system was used to achieve separation in aqueous conditions.

Funder

Basic Energy Sciences

U.S. Department of Energy

Office of Science

University of Pennsylvania

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference28 articles.

1. U.S. Department of Energy , Critical Materials Strategy , 2011 , URL: https://www.energy.gov/sites/prod/files/DOE_CMS2011_FINAL_Full.pdf

2. Recycling of rare earths: a critical review

3. Quantity Separation of Rare Earths by Liquid—Liquid Extraction. I. The First Kilogram of Gadolinium Oxide1

4. Fractional extraction of the lanthanides as their di-alkyl orthophosphates

5. D.Qi , Hydrometallurgy of Rare Earths , Elsevier Ltd , Burlington MA, USA , 2018

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