Abstract
Redox reactions involve the change of oxidation state of a compound, caused by the transfer of oxygen and/or electrons between compounds; this is the core of most chemical reactions. This chapter introduces the basic concepts of redox reactions in organic chemistry before discussing the sustainability issues around redox reactions. The various types of reagents are considered, including stoichiometric reagents, metal-based and organo-catalysts, and enzymes. The chapter then looks at approaches to greener oxidation, including epoxidation, and greener reduction, including catalyst choice, and ends with case studies on sono-chemical oxidation and waste plastic degradation.
Publisher
The Royal Society of Chemistry
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