Homoleptic octahedral Co<sup>II</sup> complexes as precatalysts for regioselective hydroboration of alkenes with high turnover frequencies-Reference-Cited by-同舟云学术

Homoleptic octahedral Co^II complexes as precatalysts for regioselective hydroboration of alkenes with high turnover frequencies

Published:2023 Issue:40 Volume:13 Page:28089-28096
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zhang Guoqi¹^ORCID,Zeng Haisu¹²,Zadori Nora¹,Marino Camila¹,Zheng Shengping²^ORCID,Neary Michelle C.²^ORCID

Affiliation:

1. Department of Sciences, John Jay College and PhD Program in Chemistry, The Graduate Center of the City University of New York, New York, 10019 NY, USA

2. Department of Chemistry, Hunter College, The City University of New York, New York, 10065 NY, USA

Abstract

Monoprotonated homoleptic complex of cobalt(ii) with 4′-pyridyl-2,2′;6′,2′′-terpyridine ligand is an efficient precatalyst for hydroboration of styrene derivatives with Markovnikov selectivity, displaying turnover frequencies up to 47 000 h−1.

Funder

National Science Foundation

Air Force Office of Scientific Research

Professional Staff Congress and City University of New York

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D3RA06113B

Reference50 articles.

1. Recent development and improvement for boron hydride-based catalytic asymmetric reduction of unsymmetrical ketones

2. A.Togni and H.Grützmacher , Catalytic Heterofunctionalization , Wiley-VCH , Weinheim , 2001

3. M. B.Smith and J.March , March's Advanced Organic Chemistry , Wiley-Interscience , Hoboken, NJ , 6th edn, 2007 , pp. 1703–1869

4. Hydrofunctionalization , Topics in Organometallic Chemistry, ed. V. P. Ananikov and M. Tanaka , Springer–Verlag , Berlin, Heidelberg , 2013 , p. 43

5. Hydroboration of Alkenes and Alkynes Employing Earth‐Abundant Metal Catalysts