Halogenoborane mediated allene cyclooligomerization
Author:
Affiliation:
1. Organisch-Chemisches Institut
2. Westfälische Wilhelms-Universität Münster
3. 48149 Münster
4. Germany
Abstract
Allene reacts with the strongly electrophilic halogenoboranes XB(C6F5)2 (X: Cl or Br) by forming a mixture of 1,3,5-trimethylenecyclohexane and the stoichiometric halogeno-borated tetramerization products.
Funder
H2020 European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04790A
Reference46 articles.
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3. Some Typical Advances in the Synthetic Applications of Allenes
4. N. Krause , Cumulenes and Allenes, Science of Synthesis , Thieme , Stuttgart, Germany , 2007 , vol. 44
5. Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles
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