Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn)-Reference-Cited by-同舟云学术

Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn)

Published:2018 Issue:13 Volume:47 Page:4534-4544
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Brugos Javier¹²³⁴⁵^ORCID,Cabeza Javier A.¹²³⁴⁵^ORCID,García-Álvarez Pablo¹²³⁴⁵^ORCID,Pérez-Carreño Enrique⁶³⁴⁵^ORCID,Polo Diego¹²³⁴⁵

Affiliation:

1. Centro de Innovación en Química Avanzada (ORFEO-CINQA)

2. Departamento de Química Orgánica e Inorgánica

3. Universidad de Oviedo

4. 33071 Oviedo

5. Spain

6. Departamento de Química Física y Analítica

Abstract

The title stannylene presents intramolecular P⋯Sn interactions and is prone to get inserted into M–Cl bonds to give a κ²Sn,P-coordinated chloridostannyl ligand.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04561A

Reference99 articles.

1. Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis

2. Unusual and rare pincer ligands: Synthesis, metallation, reactivity and catalytic studies

3. The Privileged Pincer–Metal Platform: Coordination Chemistry & Applications , ed. G. van Koten and R. A. Gossage , Springer , Cham , 2016