A catalyzed E/Z isomerization mechanism of stilbene using para-benzoquinone as a triplet sensitizer

Author:

Nakatani Kaho1,Sato Hirofumi12ORCID,Fukuda Ryoichi13ORCID

Affiliation:

1. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto-Daigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

2. Fukui Institute for Fundamental Chemistry (FIFC), Kyoto University, Kyoto 606-8103, Japan

3. Center for the Promotion of Interdisciplinary Education and Research, Elements Strategy Initiative for Catalysts and Batteries (ESICB), Kyoto University, 1-30 Goryo-Ohara, Nishikyo-ku, Kyoto 615-8245, Japan

Abstract

We investigated the mechanism of photoisomerization of stilbene via triplet state with para-benzoquinone sensitizer using the density functional theory and proposed a photocatalyst behavior of para-benzoquinone.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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