A theory for the temperature effect on the chain length dependence of the diffusivity of oligomers
Author:
Affiliation:
1. Donadeo Innovation Centre for Engineering
2. Department of Chemical and Materials Engineering
3. University of Alberta
4. Edmonton
5. Canada
Abstract
Temperature effect on the size dependence of the diffusivity of oligomers is explained by free volume theory.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SM/C9SM02505G
Reference22 articles.
1. On the Free‐Volume Model of the Liquid‐Glass Transition
2. S. Chapman and T. G.Cowling , The Mathematical Theory of Non-uniform Gases: An Account of the Kinetic Theory of Viscosity, Thermal Conduction, and Diffusion in Gases , Cambridge University Press , 1970
3. Generic van der Waals equation of state and statistical mechanical representations of the van der Waals parameters
4. Excluded volume in the generic van der Waals equation of state and the self-diffusion coefficient of the Lennard-Jones fluid
5. Voids, generic van der Waals equation of state, and transport coefficients of liquids
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