Synthesis, optical and electrochemical properties of the A–π-D–π-A porphyrin and its application as an electron donor in efficient solution processed bulk heterojunction solar cells

Author:

Vijay Kumar Challuri12,Cabau Lydia12,Koukaras Emmanuel N.34567,Sharma Ganesh D.891011,Palomares Emilio121213

Affiliation:

1. Institute of Chemical Research of Catalonia (ICIQ)

2. E-43007 Tarragona, Spain

3. Institute of Chemical Engineering Sciences

4. Foundation for Research & Technology

5. Patras, Greece

6. Molecular Engineering Laboratory

7. Department of Physics

8. R & D Center for Engineering and Science

9. JEC group of Colleges

10. Jaipur Engineering College

11. Kukas, India

12. Catalan Institution for Research and Advance Studies (ICREA)

13. E-08010 Barcelona, Spain

Abstract

A conjugated acceptor–donor–acceptor with a Zn-porphyrin core and di-cyanovinyl substituted thiophene connected at meso positions was designed, synthesized and used in BHJ solar cells. The PCE of the devices reached 5.24%.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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