Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes-Reference-Cited by-同舟云学术

Comparing the reactivity of isomeric phosphinoferrocene nitrile and isocyanide in Pd(ii) complexes: synthesis of simple coordination compounds vs. preparation of P-chelated insertion products and Fischer-type carbenes

Published:2018 Issue:45 Volume:47 Page:16082-16101
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Škoch Karel¹²³⁴⁵^ORCID,Císařová Ivana¹²³⁴⁵^ORCID,Uhlík Filip⁶²³⁴⁵^ORCID,Štěpnička Petr¹²³⁴⁵^ORCID

Affiliation:

1. Department of Inorganic Chemistry

2. Faculty of Science

3. Charles University

4. 128 40 Prague

5. Czech Republic

6. Department of Physical and Macromolecular Chemistry

Abstract

While phosphinoferrocene nitrile behaves as a functional phosphine, the isomeric isocyanide reacts by P-coordination and CN insertion, giving chelate products.

Funder

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03564D

Reference108 articles.

1. Organonitrile complexes of transition metals

2. Reactions of transition metal-coordinated nitriles

3. Additions to Metal-Activated Organonitriles

4. The Isocyanide–Cyanide Rearrangement; Mechanism and Preparative Applications

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