Syntheses and properties of 2-D and 3-D Pb–Ag heterometallic iodides decorated with ethylene polyamines at the Pb(ii) center

Author:

Shen Yali12345,Lu Jialin12345,Tang Chunying12345,Fang Wang12345,Jia Dingxian12345,Zhang Yong12345

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science

4. Dushu Lake Campus

5. Soochow University

Abstract

Novel iodides [{(en)2(PbAgI3)}]2n·nH2O (1), [(pda)2(PbAgI3)]n(2), [(tmeda)(PbAgI3)]n(3), [(trien)(PbAgI3)]n(4), [(tepa)(PbAg2I4)]n(5), and [{(dien)3(CO3)}2(Pb6Ag8I15)]nIn(6) were prepared in DMF solution.1–6represent a new type of heterometallic iodides containing coordinative organic components.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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