Bulk-like emission in the visible spectrum of colloidal LiYF4:Pr nanocrystals downsized to 10 nm

Author:

Komban Rajesh1ORCID,Spelthann Simon2ORCID,Steinke Michael2ORCID,Ristau Detlev234ORCID,Ruehl Axel3,Gimmler Christoph1ORCID,Weller Horst15ORCID

Affiliation:

1. Fraunhofer Center for Applied Nanotechnology CAN – (A Research Division of Fraunhofer Institute for Applied Polymer Research, 14476 Potsdam, Germany), Grindelallee 117, 20146 Hamburg, Germany

2. Leibniz University Hannover, Institute of Quantum Optics, Welfengarten 1, 30167 Hannover, Germany

3. Leibniz University Hannover, QUEST-Leibniz-Research School, Institute of Quantum Optics, Callinstraße 36, 30167 Hannover, Germany

4. Cluster of Excellence PhoenixD (Photonics, Optics and Engineering – Innovation Across Disciplines), Germany

5. University of Hamburg, Department of Chemistry, Grindelallee 117, 20146 Hamburg, Germany

Abstract

Herein, highly stable colloidal LiYF4:Pr3+ nanocrystals are presented for the first time. Through extensive comparison of their spectroscopic behavior with bulk crystals an unusual intense bulk like emission in the visible spectrum was observed.

Funder

Deutsche Forschungsgemeinschaft

Leibniz University Hannover

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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