Selective nitration of phenol to o-nitrophenol in the presence of metal-free reduced graphene oxide at room temperature

Author:

Mondal Sourov12345,Singh Jaydeep12345,Singh Shikha12345,Vishwakarma Sambhav12345,Mitra Kheyanath12345ORCID,Kumari Archana12345,Singh Rajshree12345ORCID,Sen Gupta Susanta K.12345ORCID,Ray Biswajit12345ORCID

Affiliation:

1. Department of Chemistry

2. Institute of Science

3. Banaras Hindu University

4. Varanasi – 221005

5. India

Abstract

Reduced graphene oxide catalyzed selective synthesis of o-nitrophenol from an equimolar mixture of phenol and nitric acid in dichloroethane at room temperature.

Funder

Department of Biotechnology, Ministry of Science and Technology

Council of Scientific and Industrial Research, India

University Grants Commission

Banaras Hindu University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference34 articles.

1. G. A. Olah , R.Malhotra and S. C.Narang , Nitration Methods and Mechanisms , VCH Publications , New York , 1989

2. Zeolite-mediated regioselective nitration of phenol in solid state

3. A. Vogel , A Text Book of Practical Organic Chemistry , Longman , London , 1978

4. J. H. Clark , Chemistry of waste Minimization , Springer Science Business Media , Dordrecht , 1st edn, 1995

5. Calcium Nitrate—A New Nitrating Agent for Nuclear Nitration of Substituted Phenols

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